Yes I have used utility poles in several frames. My shop in fact is a hodge-podge of various pole timber. Some with climbing spur marks still visible.
Roger is right in his warning about creosote. Poles treated with that should be avoided for anything but being a utility pole.
However, most North American utilities stopped using creosote as a preservative many years ago and switched to CCA ..the green stuff. Poles treated with this can be used quite safely. The preservative only penetrates about 2" and can be easily removed with the slabs. The butt end usually has more penetration because of end grain.
Look for the suppliers stamp on the pole, it's located 10' from the butt end. It will tell you the species of wood, what it's treated with, the length, the class, the date it was done, and the suppliers name. A "WRC, CCA, 65, 2, 1995, Kirkland" tells you all you need. The lower the class number the fatter the pole is. A class 4 is a small service pole in a farmers yard. A class 1 is a future 12x12 30' tie beam.
Western Red, Southern Yellow Pine, Red Pine, Lodgepole, DF are all wood you can find in a pole. No EWP though.
One other thing, older WRC poles, like from the 60's and early 70's were treated with creosote at the butt only, no treatment of any kind above grade. Cut the butt off and you have beautiful cedar worthy of any project, timber of otherwise.
My 2 cents