Keep in mind this is a response from a non-PE, mechanical engineer and timber frame amateur.
Making the following assumptions:
- rafters are only bearing on a plate and ridge beam (opposing rafters without a structrual ridge beam makes this condition worse)
- you have 40lb/ft^2 live load and 15lb/ft^2 dead load
- the hemlock is green when you raise it
- 5/12 pitch
- There is little joinery in the rafters (tusk tenon purlin joints are ok, but half lap or housed purlins and your collar tie would probably force the timber size to be increased)
You'd need 6x9 #1 hemlock rafters. The sag would be about 3/8".
If you stuck with a 6x6 #1 hemlock the sag would be 1-1/4" and the timber would fail or be permenantly deformed if/when a maximum load condition occurs.